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Media buttons are not working

Power Toggles music buttons work by emulating multimedia keys, similar to that of a bluetooth handsfree or a bluetooth keyboard.

So if the buttons are not working, verify that they work while using a bluetooth multimedia keyboard or a handsfree (by connecting the bluetooth device and pressing the multimedia keys).

Also note that, by default the keys are sent to android at a global level. In settings (Settings > Toggle Settings > Play/Pause Music) you could choose a target app to send the media keys to.